Stereospecific Rearrangements in Tricyclopentanoid Sesquiterpenes: The Absolute Configuration of (-)-Isocomene, (-)-β-Isocomene, and (-)-Silphinene

DOI: 10.1021/jo00075a004

Source and publish data:

Journal of Organic Chemistry p. 6171 - 6173 (1993)

Update date:2022-08-04

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Authors:

Fitjer, Lutz

Monzo-Oltra, Honorato

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Article abstract of DOI:10.1021/jo00075a004

The determination of the absolute configuration of (-)-isocomene ((-)-9), (-)-β-isocomene ((-)-3), and (-)-silphinene ((-)-15) by correlation with (-)-modhephene ((-)-(3aR,4R,6aS)-4) via stereospecific rearrangements is described.

Full text of DOI:10.1021/jo00075a004

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