Reactions of the Terminal Rhenium Acetylide Complex Re(η5-C5H5)(NO)(PPh3)(CCH) and Butyllithium; Generation, Alkylation and Stannylation of Lithiocarbide Complexes of the Formula Re(η5-C5H4X)(NO)(PPh3)(CCLi) (X = H, Li)

DOI: 10.1039/c39910001360

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1360 - 1362 (1991)

Update date:2022-08-02

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Authors:

Ramsden, James A.

Agbossou, Francine

Senn, Dwayne R.

Gladysz, J. A.

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Article abstract of DOI:10.1039/c39910001360

The title reaction gives, depending upon stoichiometry and conditions, Re(η⁵-C5H5)(NO)(PPh3)(C<*>CLi) and Re(η⁵-C5H4Li)(NO)(PPh3)(C<*>Li); the first transition metal-alkali metal carbide complexes which are in turn derivatized by car

Full text of DOI:10.1039/c39910001360

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