BIOMIMETIC ENTRY TO ACYCLIC TERPENE SYNTHESIS. A NOVEL REARRANGEMENT OF ALLYL ETHER CATALYZED BY ORGANOALUMINUM REAGENTS

DOI: 10.1016/S0040-4039(00)87225-1

Source and publish data:

Tetrahedron Letters p. 1933 - 1936 (1982)

Update date:2022-08-03

Topics:

Authors:

Yamamura, Yoshihiro

Umeyama, Kensuke

Maruoka, Keiji

Yamamoto, Hisashi

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Article abstract of DOI:10.1016/S0040-4039(00)87225-1

The intramolecular prenyltransfer reaction is accomplished by the rearrangement of allyl ethers with (2,6-di-tert-butyl-4-methylphenoxy)methylaluminum trifluoromethanesulfonate.The present method provides a simple and highly efficient synthesis of lavandulol.

Full text of DOI:10.1016/S0040-4039(00)87225-1

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