PREPARATION AND REPLACEMENT REACTIONS OF PENTACARBONYL(DIMETHYLSULFOXIDO)VANADATE(-I)

DOI: 10.1016/S0022-328X(00)87642-1

Source and publish data:

Journal of Organometallic Chemistry p. 151 - 154 (1982)

Update date:2022-07-29

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Authors:

Ihmels, Klaus

Rehder, Dieter

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Article abstract of DOI:10.1016/S0022-328X(00)87642-1

The photo-reaction between and DMSO yields (with DMSO presumably bonded via sulfur).Thermally induced replacement of DMSO by a ligand L affords , where L=pyridine, CN^-, PCy3, Ph2As(CH2)2PPh2, Ph2P(CH2)2PPh2, Ph2P(CH2)2PEt2, PhP(CH2CH2PPh2)2 and P(CH2CH2PPh2)3.IR, 31P and 51V NMR spectra are reported.

Full text of DOI:10.1016/S0022-328X(00)87642-1

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