CHIRAL DISCRIMINATION IN ORGANOMETALLIC SYSTEMS. REACTION OF + WITH (R)-(+)589-1-PHENYLETHYLAMINE

DOI: 10.1016/S0022-328X(00)86855-2

Source and publish data:

Journal of Organometallic Chemistry p. C5 - C8 (1982)

Update date:2022-07-29

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Authors:

Atton, J. G.

Kane-Maguire, L. A. P.

Williams, P. A.

Stephenson, G. R.

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Article abstract of DOI:10.1016/S0022-328X(00)86855-2

CD spectral studies show that kinetic diastereotopic discrimination occurs in the reaction of (R,S)-⁺ (I) with (R)-(+)₅₈₉-1-phenylethylamine (II) in CH3CN.This process involves initial attack by the amine at

Full text of DOI:10.1016/S0022-328X(00)86855-2

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Product name:Fe(CO)3((C₆H₅CH(CH₃)NH₂)C₆H₆OCH₃)⁽¹⁺⁾*(BF₄)^(1-)=Fe(CO)3((C₆H₅CH(CH₃)NH₂)C₆H₆OCH₃)(BF₄)

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