REGIOSELECTIVE ADDITIONS OF ELECTROPHILES TO OLEFINS REMOTELY PERTURBED. THE CARBONYL GROUP AS A HOMOCONJUGATED ELECTRON DONATING SUBSTITUENT.

DOI: 10.1016/S0040-4039(00)87396-7

Source and publish data:

Tetrahedron Letters p. 2563 - 2566 (1982)

Update date:2022-08-04

Topics: Carbonyl group Regioselective

Authors:

Carrupt, Pierre-Alain

Vogel, Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)87396-7

Electrophiles attack preferentially at the C(5) position of 2-norborn-5-enone and 2-bicyclo<2.2.2>oct-5-enone whereas the C(6) position is preferred for 2-chloronorborn-5-ene-2-carbonitriles and 2-chlorobicyclo<2.2.2>oct-5-ene-2-carbonitriles.

Full text of DOI:10.1016/S0040-4039(00)87396-7

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