REGIOSELECTIVE ADDITIONS OF ELECTROPHILES TO OLEFINS REMOTELY PERTURBED. THE CARBONYL GROUP AS A HOMOCONJUGATED ELECTRON DONATING SUBSTITUENT.

DOI: 10.1016/S0040-4039(00)87396-7

Source and publish data:

Tetrahedron Letters p. 2563 - 2566 (1982)

Update date:2022-08-04

Topics: Carbonyl group Regioselective

Authors:

Carrupt, Pierre-Alain

Vogel, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)87396-7

Electrophiles attack preferentially at the C(5) position of 2-norborn-5-enone and 2-bicyclo<2.2.2>oct-5-enone whereas the C(6) position is preferred for 2-chloronorborn-5-ene-2-carbonitriles and 2-chlorobicyclo<2.2.2>oct-5-ene-2-carbonitriles.

Full text of DOI:10.1016/S0040-4039(00)87396-7

Products guided by the article

Product name:1-[(1R,5R)-5-(2-Chloro-2,2-dimethoxy-ethyl)-cyclopent-2-enylsulfanyl]-2-nitro-benzene

Cas No:83205-17-8

R&D Labs maybe for 83205-17-8

Jinan Great Chemical Co.,Ltd.

Contact:+86-531-58668191 58668193 58668196 58661173

Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Shanghai Hope Chem Co., Ltd

website:http://www.hope-chem.com

Contact:86-21-58090396-805

Address:Floor 4, Building 5, No.588 Tianxiong Road, Zhoupu International Medical Zone, ShangHai, China
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Liaoyang hengye Chemical Co., Ltd.

Contact:86-419-5850866

Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China

Relevant to this article

Efficient approach to fluvirucins b₂-b₅, sch 38518, and sch 39185. first synthesis of their aglycon, via CM and RCM reactions

Doi:10.1021/ol901030f
(2009)
CC chemokine receptor-3 (CCR3) antagonists: Improving the selectivity of DPC168 by reducing central ring lipophilicity

Doi:10.1016/j.bmcl.2007.03.065
(2007)
Selective Preparation. 40. A New Preparative Route to 8,16-Dimethyl<2.2>metacyclophan-1-ene

Doi:10.1021/jo00198a029
(1984)
A FACILE SYNTHESIS OF α-GLUCOSIDES AND α-RIBOSIDES FROM THE CORRESPONDING 1-O-ACYL SUGARS AND ALCOHOLS IN THE PRESENCE OF TRITYL PERCHLORATE

Doi:10.1246/cl.1984.907
(1984)
Doi:10.1039/jr9490000326
(1949)
Copper(I) Oxide/N,N′-Bis[(2-furyl)methyl]oxalamide-Catalyzed Coupling of (Hetero)aryl Halides and Nitrogen Heterocycles at Low Catalytic Loading

Doi:10.1002/adsc.201700026
(2017)

Article Doi