Tetrahedron p. 927 - 936 (1982)
Update date:2022-08-04
Topics:
Spitzner, R.
Mielke, D.
Scholz, D.
Schroth, W.
Preiss, A.
Thiocarbamides and thioureas 1 react as ambident systems with β-chlorovinyl ketones 2 to give the S-<(Z)-ketovinyl>-salts 3-5.Those obtained from monoprotic 1 undergo deprotonation, yielding isolable S-<(Z)-ketovinyl>thioimidateesters or -isothioureas 6 r
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