KETOVINYLIERUNG VON THIOCARBONAMIDEN UND THIOHARNSTOFFEN. ZUR AMBIDENZ DER THIOAMIDFUNKTION

DOI: 10.1016/0040-4020(82)85072-2

Source and publish data:

Tetrahedron p. 927 - 936 (1982)

Update date:2022-08-04

Topics:

Authors:

Spitzner, R.

Mielke, D.

Scholz, D.

Schroth, W.

Preiss, A.

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Article abstract of DOI:10.1016/0040-4020(82)85072-2

Thiocarbamides and thioureas 1 react as ambident systems with β-chlorovinyl ketones 2 to give the S-<(Z)-ketovinyl>-salts 3-5.Those obtained from monoprotic 1 undergo deprotonation, yielding isolable S-<(Z)-ketovinyl>thioimidateesters or -isothioureas 6 r

Full text of DOI:10.1016/0040-4020(82)85072-2

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