Regio- and Stereo-selectivity in the Hydrogenation of Aryl Phosphines by Niobium Aryloxide Compounds

DOI: 10.1039/c39950000849

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 849 - 852 (1995)

Update date:2022-08-04

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Authors:

Potyen, Mark C.

Rothwell, Ian P.

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Article abstract of DOI:10.1039/c39950000849

The sequential hydrogenation of the three aryl rings in PPh3 by the catalyst system /3BuⁿLi occurs with relative rates of 39:28:1; NMR analysis of the PhPCy2 obtained from and shows a predominantly all cis hydrogenation of both aryl rings has occurred.

Full text of DOI:10.1039/c39950000849

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