Isomerizations of Tertiary Allylamines and Ring Expanding Rearrangements by Quaternization

DOI: 10.1002/ardp.19823150904

Source and publish data:

Archiv der Pharmazie p. 749 - 760 (1982)

Update date:2022-08-03

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Authors:

Bersch, Hans-Werner

Rissmann, Ruediger

Schon, Dietmar

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Article abstract of DOI:10.1002/ardp.19823150904

1,1-Diphenyl-1-piperidino-2-propene rearranges thermally and on reaction with cyclopentanone/NaI to form the 1,1-diphenyl-3-piperidino-1-propene.In the same way the isoquinoline 8 isomerizes to the benzazocine 9, whereas the 2-vinylpyrrolidines 16 undergo

Full text of DOI:10.1002/ardp.19823150904

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