Kinetics of nucleophilic attack on coordinated organic moieties. XXVI. An extended nucleophilicity scale for nucleophilic addition to the cation +

DOI: 10.1016/0022-328X(80)83006-3

Source and publish data:

Journal of Organometallic Chemistry p. 47 - 54 (1988)

Update date:2022-08-04

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Authors:

Ghazy, Tahany

Kane-Maguire, Leon A. P.

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Article abstract of DOI:10.1016/0022-328X(80)83006-3

A nucleophilicity scale is established for the addition of ca. 40 different nucleophiles to the cyclohexadienyl ring of the cation ⁺ (I).The factors controlling nucleophilicity towards cation I are discussed, and comparisons made with data for reactions of the nucleophiles with other model organic and inorganic substrates such as MeI and trans-.

Full text of DOI:10.1016/0022-328X(80)83006-3

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