STEREOCHEMICAL STUDIES-XXIX STEREOCHEMISTRY OF THE ADDITION OF PHOSPHOROUS TRIBROMIDE TO OLEFINS

DOI: 10.1016/S0040-4020(01)91557-1

Source and publish data:

Tetrahedron p. 3145 - 3149 (1983)

Update date:2022-08-04

Topics:

Authors:

Zefirov, Nikolai S.

Zyk, Nikolai V.

Borisenko, Analtolii A.

Krysin, Mikhail Yu.

Schestakova, Tamara G.

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Article abstract of DOI:10.1016/S0040-4020(01)91557-1

The stereochemical course of PBr3 addition to a series of cycloolefins has been found to depend crucially on the olefinic structure and the reaction proceeds in highly stereoselective fashion either as trans-(cyclohexene) or as cis-(norbornene and related

Full text of DOI:10.1016/S0040-4020(01)91557-1

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