Tetrahedron Letters p. 6689 - 6692 (1999)
Update date:2022-09-26
Topics:
Coxon, Geoffrey D.
Knobl, Stefan
Roberts, Evan
Baird, Mark S.
Al Dulayymi, Juma R.
Besra, Gurdyal S.
Brennan, Patrick J.
Minnikin, David E.
(11R, 12S)-Lactobacillic acid (1) has been prepared either from D- mannitol by asymmetric cyclopropanation or from cis-cyclopropane-1, 2- dimethanol by enzymatic desymmetrisation. The syntheses of (l1S 12R)- lactobacillic acid (2) and (1R, 2S) 1- (3'-methoxycarbonylpropyl)-2- octadecylcyclopropane (26) and related analogues (27 and 28) have also been achieved.
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