AN ALDOL-TYPE REACTION OF ACETONITRILES USING DIALKYLBORYL TRIFLATE

DOI: 10.1246/cl.1982.1401

Source and publish data:

Chemistry Letters p. 1401 - 1404 (1982)

Update date:2022-08-05

Topics:

Authors:

Hamana, Hiroshi

Sugasawa, Tsutomu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1982.1401

Acetonitriles and benzaldehydes react in the presence of dialkyl boryl triflate and diisopropylethylamine in dichloromethane to give the corresponding aldol-type products in good yields under mild conditions.

Full text of DOI:10.1246/cl.1982.1401

Products guided by the article

Product name:(E)-3-Hydroxy-2-((E)-1-hydroxy-3-phenyl-allyl)-5-phenyl-pent-4-enenitrile

Cas No:84466-47-7

R&D Labs maybe for 84466-47-7

Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Zhejiang Kangfeng Chemical Co.,LTD.

Contact:+86-579-86709687

Address:Xueshizhai Industrial Zone, Weishan Town,Dongyang City, Zhejiang Province ,China
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China

Relevant to this article

Neighboring-group participation in nitrile-forming Beckmann fragmentation reactions: Synthesis of enantiopure (E)-2,3-Di-O-substituted-5-methoxypent-4- enenitriles and their conversion into pyranosylamines

Doi:10.1002/ejoc.200400498
(2004)
Synthesis, structure and emission properties of spirocyclic benzofuranones and dihydroindolones: A domino insertion-coupling-isomerization-Diels-Alder approach to rigid fluorophores

Doi:10.1002/chem.200700759
(2008)
Identification of a new series of non-peptidic NK₃ receptor antagonists

Doi:10.1016/j.bmcl.2010.12.135
(2011)
Ribofuranose-ring cleavage of purine nucleosides with diisobutylaluminum hydride: Convenient method for the preparation of purine acyclonucleosides

Doi:10.1016/S0040-4020(97)10098-9
(1997)
o-Benzosemiquinone and Its Metal Chelates. Electron Spin Resonance Investigation of Radicals from the Photolysis of Catechol in the Presene of Complexing Metal Ions

Doi:10.1021/ja00370a018
(1982)
The chirality of dendrimer-based supramolecular complexes

Doi:10.1039/b413724h
(2005)

Article Doi