Journal of Fluorine Chemistry p. 159 - 170 (1982)
Update date:2022-07-30
Topics:
Plevey, Raymond G.
Rendell, Richard W.
Tatlow, John Colin
Pyridine has been fluorinated over caesium tetrafluorocobaltate(III) (CsCo(III)F4) at 300-400 deg C to give a mixture of undecafluoro-N-methyl-pyrrolidine, bis(trifluoromethyl)amine, pentafluoropyridine and several polyfluoropyridines; the product composition depend to some extent on the geometry of the reactor.The fluorinations of pentafluoropyridine, piperidine and undecafluoropiperidine were also investigated.
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Doi:10.1016/S0040-4039(00)88719-5
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(2011)Doi:10.1016/S0020-1693(00)80893-2
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