Tetrahedron Letters p. 4375 - 4378 (1982)
Update date:2022-08-05
Topics:
Adenmbri, G.
Camparini, A.
Ponticelli, F.
3-Methylisoxazolo(4,5-c)pyridine 1 on reduction with BH3*THF gave, via the isolable complex 4, the tetrahydroisoxazolopyridine 5.The presence of two chlorine atoms at the 4 and 6 positions directed borane attack to the isoxazole ring, yielding the aminoethylpyridine 8.Both types of reduction were obtained with 6-chloroisoxazolo(4,5-c)pyridine 7.
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