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AN IMPORTANT ROLE PLAYED BY DIANIONES IN THE HIGHLY EFFICIENT MACROCYCLE FORMATION BY AN INTRAMOLECULAR ALKYLATION METHOD: APPLICATION TO THE SYNTHESIS OF ZEARALENONE

DOI: 10.1016/S0040-4039(00)85600-2

Source and publish data:

Tetrahedron Letters p. 4361 - 4364 (1982)

Update date:2022-08-04

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Authors:

Takahashi, TakashiTakahashi, Takashi

Nagashima, ToshiharuNagashima, Toshiharu

Ikeda, HiroshiIkeda, Hiroshi

Tsuji, JiroTsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(00)85600-2

A new synthetic method for macrolides based on intramolecular alkylation of dianions, generated from phenylthiomethyl group and protected cyanohydrin, is reported.The use of dianions for the cyclization has several characteristic features; (1) Control of

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Full text of DOI:10.1016/S0040-4039(00)85600-2

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