CARBON-CARBON BOND FORMING REACTION ASSISTED BY SILICON TRANSFER. THE REACTION BETWEEN NITRONES AND KETENE SILYL ACETALS

Article abstract of DOI:10.1246/cl.1982.1787

Nitrones reacted with ketene silyl acetals at room temperature to afford β-silyloxyamino esters in high yields.The stereochemistry of the products was assigned on the basis of NMR spectral data.A mechanism involving initial silicon transfer from ketene si