Tetrahedron Letters p. 4251 - 4254 (1982)
Update date:2022-07-30
Topics:
Lombaert,Stephane de
Lesur, Brigitte
Ghosez, Leon
The lithio derivative of 2-diethylamino-4-phenylthio-2-butenonitrile is a practical equivalent of the unknown β-carboxyl-vinyl anion, as shown by its facile alkylation with alkyl halides, aldehydes and α-enones, followed by hydrolysis, oxidation and elimination.
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