Chemistry Letters p. 93 - 96 (1983)
Update date:2022-08-03
Topics:
Asami, Masatoshi
Mukaiyama, Teruaki
α-benzyloxy aldehydes having a chiral tertiary center at α-carbon atom are synthesized in high enantiomeric excess by successive treatment of 2-methoxycarbonyl-3-phenyl-1,3-diazabicyclo<3.3.0>octane with diisobutylaluminum hydride (DIBAL-H) and Grignard reagents.The asymmetric reaction is applied to the total synthesis of exo-(+)-brevicomin.
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Doi:10.1021/jo00155a057
(1983)Doi:10.1039/DT9860002105
(1986)Doi:10.1021/acs.jnatprod.7b00789
(2017)Doi:10.1016/j.inoche.2010.02.013
(2010)Doi:10.1007/s11172-014-0563-1
(2014)Doi:10.1248/cpb.49.988
(2001)
