METALLORGANISCHE LEWIS-SAEUREN METALLKOMPLEXE MIT SCHWACH KOORDINIERTEN LIGANDEN. XI. ACETYLVERBRUECKTE KATIONISCHE KOMPLEXE VON MOLYBDAEN, EISEN UND MANGAN; STRUKTUR VON 2-η2-CH3CO)Mo(CO)2(?-C5H5)>+BF4-

DOI: 10.1016/S0022-328X(00)98527-9

Source and publish data:

Journal of Organometallic Chemistry p. 333 - 342 (1983)

Update date:2022-09-26

Topics:

Authors:

Suenkel, Karlheinz

Schloter, Klaus

Beck, Wolfgang

Ackermann, Klaus

Shubert, Ulrich

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)98527-9

The highly reactive complexes (?-C5H5)(CO)3MoX (X=FBF3, FSbF5) react with (?-C5H5)(CO)3MoCH3, (?-C5H5)(CO)2FeCH3 or (?-C5H5)(CO)2FeCOCH3 and cis-, trans-Ph3P(CO)4MnCH3 to give <(?-C5H5)(CO)2Mo(μ₂-η²-CH3CO)Mo(CO)2(?-C5H5)>⁺ BF4^- (I), <(?-C5H5)(CO)2Fe-C(CH3)O-Mo(CO)3(?-C5H5)>⁺ SbF6^- (II) and <(Ph3P)(CO)4Mn-C(CH3)O-Mo(CO)3(?-C5H5)>⁺ BF4^- (II), respectively.The X-ray structure of I has been determined.It shows a symmetrical acetyl bridge of the type .

Full text of DOI:10.1016/S0022-328X(00)98527-9

Products guided by the article

Product name:μ-acetyl-O-(tricarbonylcyclopentadienylmolybdenum)-C-(tetracarbonyltriphenylphosphinemanganese) tetrafluoroborate

Cas No:85107-91-1

R&D Labs maybe for 85107-91-1

CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Taixing Shenfeng Chemical Co., Ltd.

Contact:+86-523-87117033, 87117666

Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.
Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China
Compro Shijiazhuang Fine Chemical Co., Ltd

Contact:0086-311-89689838

Address:Economic and Technological Development Zone of Shijiazhuang,Hebei

Relevant to this article

A novel synthesis, including asymmetric synthesis, of α-quaternary α-amino acid methyl esters from ketones via sulfinyloxiranes

Doi:10.1016/j.tetlet.2005.02.111
(2005)
1,3-Dioxo-4-methyl-2,3-dihydro-1H-pyrrolo[3,4-c]quinolines as potent caspase-3 inhibitors

Doi:10.1016/j.bmcl.2005.02.027
(2005)
Carbon-sulfur bond formation from 2-halochalcogenophenes via copper catalyzed thiol cross-coupling

Doi:10.1016/j.tetlet.2005.02.102
(2005)
Syntheses, optical and electrochemical properties of 4,4′-bis-[2-(3, 4-dibutyl-2-thienylethynyl)]biphenyl and its oligomers

Doi:10.1016/j.tet.2005.01.133
(2005)
Effects of polymer architecture and nanoenvironment in acylation reactions employing dendritic (Dialkylamino)pyridine catalysts

Doi:10.1021/ma050701m
(2005)
Preparative fluorous mixture synthesis of diazonium-functionalized oligo(phenylene vinylene)s

Doi:10.1021/jo048051s
(2005)

Article Doi