Journal of Organometallic Chemistry p. 333 - 342 (1983)
Update date:2022-09-26
Topics:
Suenkel, Karlheinz
Schloter, Klaus
Beck, Wolfgang
Ackermann, Klaus
Shubert, Ulrich
The highly reactive complexes (?-C5H5)(CO)3MoX (X=FBF3, FSbF5) react with (?-C5H5)(CO)3MoCH3, (?-C5H5)(CO)2FeCH3 or (?-C5H5)(CO)2FeCOCH3 and cis-, trans-Ph3P(CO)4MnCH3 to give <(?-C5H5)(CO)2Mo(μ2-η2-CH3CO)Mo(CO)2(?-C5H5)>+ BF4- (I), <(?-C5H5)(CO)2Fe-C(CH3)O-Mo(CO)3(?-C5H5)>+ SbF6- (II) and <(Ph3P)(CO)4Mn-C(CH3)O-Mo(CO)3(?-C5H5)>+ BF4- (II), respectively.The X-ray structure of I has been determined.It shows a symmetrical acetyl bridge of the type
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