METALLORGANISCHE LEWIS-SAEUREN METALLKOMPLEXE MIT SCHWACH KOORDINIERTEN LIGANDEN. XI. ACETYLVERBRUECKTE KATIONISCHE KOMPLEXE VON MOLYBDAEN, EISEN UND MANGAN; STRUKTUR VON 2-η2-CH3CO)Mo(CO)2(?-C5H5)>+BF4-

DOI: 10.1016/S0022-328X(00)98527-9

Source and publish data:

Journal of Organometallic Chemistry p. 333 - 342 (1983)

Update date:2022-09-26

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Authors:

Suenkel, Karlheinz

Schloter, Klaus

Beck, Wolfgang

Ackermann, Klaus

Shubert, Ulrich

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Article abstract of DOI:10.1016/S0022-328X(00)98527-9

The highly reactive complexes (?-C5H5)(CO)3MoX (X=FBF3, FSbF5) react with (?-C5H5)(CO)3MoCH3, (?-C5H5)(CO)2FeCH3 or (?-C5H5)(CO)2FeCOCH3 and cis-, trans-Ph3P(CO)4MnCH3 to give <(?-C5H5)(CO)2Mo(μ₂-η²-CH3CO)Mo(CO)2(?-C5H5)>⁺ BF4^- (I), <(?-C5H5)(CO)2Fe-C(CH3)O-Mo(CO)3(?-C5H5)>⁺ SbF6^- (II) and <(Ph3P)(CO)4Mn-C(CH3)O-Mo(CO)3(?-C5H5)>⁺ BF4^- (II), respectively.The X-ray structure of I has been determined.It shows a symmetrical acetyl bridge of the type .

Full text of DOI:10.1016/S0022-328X(00)98527-9

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