Journal of Organometallic Chemistry p. 245 - 250 (1983)
Update date:2022-08-04
Topics:
Hoberg, Heinz
Riegel, Hans Josef
Acetylene and 1-alkynes react with carbon monoxide under basic conditions (amines) with nickel(II) complexes, L2NiBr2 (L=Et2NH, (C6H5)3P), to give acetylencarboxamides with maintenance of the triple bond.Intermediates are isolated, characterised and a mechanism is proposed.
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