NICKEL(II) INDUZIERTE C-C VERKNUEPFUNG ZWISCHEN KOHLENMONOXID UND ALKINEN UNTER ERHALT DER DREIFACHBINDUNG

DOI: 10.1016/S0022-328X(00)98511-5

Source and publish data:

Journal of Organometallic Chemistry p. 245 - 250 (1983)

Update date:2022-08-04

Topics:

Authors:

Hoberg, Heinz

Riegel, Hans Josef

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)98511-5

Acetylene and 1-alkynes react with carbon monoxide under basic conditions (amines) with nickel(II) complexes, L2NiBr2 (L=Et2NH, (C6H5)3P), to give acetylencarboxamides with maintenance of the triple bond.Intermediates are isolated, characterised and a mechanism is proposed.

Full text of DOI:10.1016/S0022-328X(00)98511-5

Products guided by the article

Product name:((C₆H₅)3P)2Ni(C₂H)Br(CO)

Cas No:85233-96-1

R&D Labs maybe for 85233-96-1

Shanghai Synmedia Chemical Co., Ltd

Contact:+86-21-38681880

Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Puyang Willing Chemicals Co.,Ltd.

Contact:86-393-4840366

Address:Puyang Henan China
Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District

Relevant to this article

Copper-catalyzed allylic hydroxyamination and amination of alkenes with Boc-hydroxylamine

Doi:10.1016/j.tetlet.2005.01.024
(2005)
A practical diastereoselective synthesis of syn-α- hydroxyaminonitriles

Doi:10.1055/s-2005-864838
(2005)
In situ conversion of a Ru metathesis catalyst to an isomerization catalyst

Doi:10.1039/b400229f
(2004)
Substituent effects in the ring-chain tautomerism of 4-aryl-1,3,4,6,7,11b- hexahydro-2H-pyrimido[6,1-a]isoquinolines

Doi:10.1016/j.tet.2005.03.067
(2005)
Enones with Strained Double Bonds. 8. The Bicyclo<3.2.1>octane Systems

Doi:10.1021/jo00158a014
(1983)
Visible-light-induced phenylchalcogenyl-oxygenation of allenes having aryl or electron withdrawing substituents with ambient air as a sole oxidant

Doi:10.1039/c6ob02033j
(2016)

Article Doi