New route to 3-deoxy-2-ulosonic acids; total synthesis of KDO and KDN

DOI: 10.1016/S0040-4039(97)01484-6

Source and publish data:

Tetrahedron Letters p. 6415 - 6418 (1997)

Update date:2022-08-05

Topics:

Authors:

Tsukamoto, Hirokazu

Takahashi, Takashi

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Article abstract of DOI:10.1016/S0040-4039(97)01484-6

Syntheses of KDO and KDN by alkylation of 2-alkoxy-2-cyanoacetate anion, an acyl anion equivalent of alkyl glyoxylate, with a sugar-derived iodide and triflate are described.

Full text of DOI:10.1016/S0040-4039(97)01484-6

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