
Tetrahedron Letters p. 4509 - 4512 (1982)
Update date:2022-08-03
Topics:
Fleet, G. W. J.
Gough, M. J.
Enantiospecific syntheses of 1S,6S-3,7-dioxabicyclo<4,3,0>non-4-en-8-one (1) and of the enantiomer (2) from D- and L-arabinose respectively have been achieved by two different routes.The conversion of (1) to 6S-(3R-acetanilido)-3,6-dihydro-2H-pyranyl-N,N-dimethylacetamide (3), a key intermediate in the synthesis of pseudomonic acids, is described.
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