SINGLET OXYGENATION OF 7-ARYL AND 7-ALKYL-1,3,5-CYCLOHEPTATRIENES: SUBSTITUENT EFFECTS ON THE PRODUCT DISTRIBUTION OF TROPILIDENE- AND NORCARADIENE-DERIVED ENDOPEROXIDES

DOI: 10.1016/S0040-4039(00)85744-5

Source and publish data:

Tetrahedron Letters p. 4907 - 4910 (1982)

Update date:2022-08-05

Topics:

Authors:

Adam, Waldemar

Rebollo, Hector

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Article abstract of DOI:10.1016/S0040-4039(00)85744-5

The N/T ratio, i. e. the proportion of norcaradiene (N) versus tropilidene (T) endoperoxides in the cycloaddition of singlet oxygen with 7-substituted 1,3,5-cycloheptatrienes, decreases in the order p-ClC6H4 > C6H5 >p-MeOC6H4 and t-Bu > i-Pr > Et > Me, pr

Full text of DOI:10.1016/S0040-4039(00)85744-5

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