ARYLDIAZENIDO, ARYLDIAZENE, AND ARYLHYDRAZIDO COMPLEXES. FURTHER STUDIES OF ortho-METALATED IRIDIUM COMPLEXES DERIVED FROM REACTIONS OF ARYLDIAZONIUM IONS WITH IrH(CO)(PPh3)3 AND IrH(CO)2(PPh3)2

Article abstract of DOI:10.1016/S0022-328X(00)98634-0

The syntheses are described of ortho-metalated iridium arylhydrazido complexes BF4, where X=H, 4-F, 3-F, 2-F, 4-OMe, 2-OMe, 2-NO2, 3-NO2, 3-CH3, 4-CH3 and 2-CF3 from the reactions of the corresponding arenediazonium tetrafluorobo