OXIDATION OF 2-SUBSTITUTED ALLYLSILANE TO CONJUGATED ENAL USING HYPERVALENT ORGANOIODINE COMPOUND AND SYNTHESIS OF α-METHYLENE γ- AND δ-LACTONES

DOI: 10.1016/S0040-4039(00)81525-7

Source and publish data:

Tetrahedron Letters p. 777 - 780 (1983)

Update date:2022-09-26

Topics:

Authors:

Ochiai, Masahito

Fujita, Eiichi

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Article abstract of DOI:10.1016/S0040-4039(00)81525-7

2-Substituted allylsilanes 1 on treatment with iodobenzene and boron trifluoride etherate in dioxane afforded conjugated enals 2 directly in good yield, from which α-methylene γ- and δ-lactones 7 were synthesized.

Full text of DOI:10.1016/S0040-4039(00)81525-7

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