Tetrahedron Letters p. 4311 - 4314 (1982)
Update date:2022-09-26
Topics:
Jost, Philippe
Forestiere, Alain
Sillion, Bernard
Le Perchec, Pierre
The base-initiated thermolysis of diaryl carbonates leads to diaryl ethers.Kinetics evidences (Ea= 26 kcal.mole-1 )are given, showing that reaction proceeds via SNAr mechanism.Phenoxide is recognised as the active species.
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Doi:10.1248/cpb.28.3649
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