THERMOLYSE DES CARBONATES D'ARYLE INITIEE PAR LES BASES : I-MECANISME PAR SNAR DANS LE CAS DES CARBONATES D'ARYLE PORTEURS DE GROUPES ELECTRO-ATTRACTEURS IDENTIQUES.

DOI: 10.1016/S0040-4039(00)85587-2

Source and publish data:

Tetrahedron Letters p. 4311 - 4314 (1982)

Update date:2022-09-26

Topics:

Authors:

Jost, Philippe

Forestiere, Alain

Sillion, Bernard

Le Perchec, Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)85587-2

The base-initiated thermolysis of diaryl carbonates leads to diaryl ethers.Kinetics evidences (Ea= 26 kcal.mole^-1 )are given, showing that reaction proceeds via SNAr mechanism.Phenoxide is recognised as the active species.

Full text of DOI:10.1016/S0040-4039(00)85587-2

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