THE DIELS-ALDER REACTION OF METHYL PROPIOLATE WITH 1-VINYLCYCLOALKENES

DOI: 10.1016/S0040-4039(00)81375-1

Source and publish data:

Tetrahedron Letters p. 241 - 244 (1983)

Update date:2022-08-05

Topics:

Authors:

Markgraf, J. Hodge

Greeno, Edward W.

Miller, Michael D.

Zaks, William J.

Lee, George A.

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Article abstract of DOI:10.1016/S0040-4039(00)81375-1

The Diels-Alder reaction of methyl propiolate with 1-vinylcycloalkenes was used to assess the influence of ring strain on the regioselectivity of such cycloadditions: the ratio of 1,2,3- to 1,2,4-adducts increased with increasing size of the cycloalkene.

Full text of DOI:10.1016/S0040-4039(00)81375-1

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