HOMOLOGATION OF N-ALKANES USING DIAZOESTERS AND RHODIUM(III)PORPHYRINS. ENHANCED ATTACK ON PRIMARY C-H BONDS.

DOI: 10.1016/S0040-4039(00)85590-2

Source and publish data:

Tetrahedron Letters p. 4321 - 4324 (1982)

Update date:2022-07-30

Topics: Homologation Diazoesters

Authors:

Callot, H.J.

Metz, F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)85590-2

Carbethoxycarbene, from ethyl diazoacetate and rhodium(III)porphyrins, inserted into methyl C-H bonds of n-alkenes (C6 to C12) with yields up to 20-25 percent corresponding to a large increase of the primary/secondary selectivity.

Full text of DOI:10.1016/S0040-4039(00)85590-2

Products guided by the article

Product name:Heptanoic acid, 3-propyl-, ethyl ester

Cas No:86051-38-9

R&D Labs maybe for 86051-38-9

Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town
Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China

Relevant to this article

Synthesis of 1,2,4-triazolo[1,5-d]-1,2,4-triazine-5-thiones

Doi:10.1002/jhet.5570420544
(2005)
Development of urea and thiourea kynurenamine derivatives: Synthesis, molecular modeling, and biological evaluation as nitric oxide synthase inhibitors

Doi:10.1002/cmdc.201500007
(2015)
Glycosylation of acid sensitive acceptors. Synthesis of (2,3-epoxy-1-propyl) glycosides

Doi:10.1016/j.carres.2005.07.010
(2005)
In vitro biosynthesis of the antitumor agent azinomycin B

Doi:10.1021/ol052987l
(2006)
Derivatization of phosphopeptides with mercapto- and amino-functionalized conjugate groups by phosphate elimination and subsequent Michael addition

Doi:10.1039/b505573c
(2005)
Design, synthesis and anticancer activity of fluorocyclopentenyl-purines and – pyrimidines

Doi:10.1016/j.ejmech.2018.06.003
(2018)

Article Doi