HOMOLOGATION OF N-ALKANES USING DIAZOESTERS AND RHODIUM(III)PORPHYRINS. ENHANCED ATTACK ON PRIMARY C-H BONDS.

DOI: 10.1016/S0040-4039(00)85590-2

Source and publish data:

Tetrahedron Letters p. 4321 - 4324 (1982)

Update date:2022-07-30

Topics: Homologation Diazoesters

Authors:

Callot, H.J.

Metz, F.

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Article abstract of DOI:10.1016/S0040-4039(00)85590-2

Carbethoxycarbene, from ethyl diazoacetate and rhodium(III)porphyrins, inserted into methyl C-H bonds of n-alkenes (C6 to C12) with yields up to 20-25 percent corresponding to a large increase of the primary/secondary selectivity.

Full text of DOI:10.1016/S0040-4039(00)85590-2

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