Journal of Organic Chemistry p. 2572 - 2576 (1983)
Update date:2022-08-03
Topics:
Patterson, John W.
Pfister, Jurg R.
Wagner, Paul J.
Murthy, D. V. Krishna
The synthesis of (7(tert-butyldimethylsiloxy)hepta-3,4-dien-1-yl)triphenylphosphonium iodide (1) is described.The ylide derived from 1 undergoes highly stereoselective Wittig reactions with aliphatic aldehydes to give a series of (7Z)-nonadeca-3,4,7-trien-1-ols (4) which were transformed into arachidonic acid analogues including (8Z,11Z,14Z)-eicosa-4,5,8,11,14-pentaenoic acid (9).
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Doi:10.1002/ardp.200300763
(2004)Doi:10.1055/s-1983-30276
(1983)Doi:10.1039/c39820001421
(1982)Doi:10.1039/c8cc06612d
(2018)Doi:10.1039/b502181b
(2005)Doi:10.1021/jo050669u
(2005)
