New aryl phosphinite ligands avoiding ortho-metallation: Synthesis and molecular structures of trans-[PdCl2(PPh2OR)2] and trans-[Rh(CO)Cl(PPh2OR)2] (R = 2,4,6-Me 3C6H2

DOI: 10.1016/j.ica.2005.04.041

Source and publish data:

Inorganica Chimica Acta p. 3417 - 3422 (2005)

Update date:2022-08-04

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Authors:

Chahen, Ludovic

Karmazin-Brelot, Lydia

Süss-Fink, Georg

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Article abstract of DOI:10.1016/j.ica.2005.04.041

The new aryl phosphinites PPh₂OR (R = 2,4,6-Me₃C ₆H₂, 1; R = 2,6-Ph₂C₆H₃, 2) have been prepared from chlorodiphenylphosphine and the corresponding phenols. In these ligands, the

Full text of DOI:10.1016/j.ica.2005.04.041

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Product name:trans-[PdCl₂((2,6-diphenylphenyl)diphenylphosphinite)2]

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