Ene Reaction Mechanisms. 2. Regioselectivity with N-Aryl-N'-p-tosylsulfur Diimides as Enophiles. Crystal Structure of N-(Pentafluorophenyl)-N'-p-tosylsulfur Diimide

DOI: 10.1021/jo00165a010

Source and publish data:

Journal of Organic Chemistry p. 2833 - 2837 (1983)

Update date:2022-08-05

Topics:

Authors:

Muensterer, Heribert

Kresze, Guenter

Lamm, Viktor

Gieren, Alfred

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00165a010

The ene reactions of sulfur diimides TosNSNAr (1;Ar = C6H5, 4-O2NC6H4, and C6F5) with 2-methyl-2-butene (2) have been investigated.The products undergo a <2,3> sigmatropic rearrangement.The structures of these rearranged products have been determined.Taki

Full text of DOI:10.1021/jo00165a010

Products guided by the article

Product name:Benzenesulfonamide, 4-methyl-N-(2-methyl-2-butenyl)-N-[[(4-nitrophenyl)amino]thio]-, (E)-

Cas No:86410-97-1

R&D Labs maybe for 86410-97-1

Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
HUNAN OUYA BIOLOGICAL CO.,LTD

Contact:+8613400661290

Address:No 908,Kangwan Rd, Liuyang Economic
Tianjin Tongde Biological Technology Co., Ltd.

Contact:86-22-23309138

Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China

Relevant to this article

STUDIES ON THE EFFECT OF REMOTE SUBSTITUENTS ON STEREOREACTIVITY. III. INFLUENCE OF DIRECT ELECTRONIC ACTIVATION OF THE DIPOLAROPHILIC DOUBLE-BOND ON THE COURSE OF DIAZOALKANES CYCLOADDITION TO 7 - HALONORBORNADIENES

Doi:10.1016/S0040-4039(00)81664-0
(1983)
Synthesis and anti-cancer activity of dinuclear platinum(II) complexes containing bis(thioalkyl)dicarba-closo-dodecaborane(12) ligands

Doi:10.1039/b508340k
(2005)
ON THE REACTION OF PRIMARY ALIPHATIC AMINES WITH 1,2-NAPHTHOQUINONE-4-SULFONIC ACID

Doi:10.1246/cl.1983.693
(1983)
Phosphorescent oxygen sensor with dendritic protection and two-photon absorbing antenna

Doi:10.1021/ja052947c
(2005)
Electrophilic cyclization of 2-(1-alkynyl)-2-alken-1-ones using the I ₂/K₃PO₄ system: An efficient synthesis of highly substituted iodofurans

Doi:10.1021/ol051659i
(2005)
Conformation of gem-disubstituted alkylarylpiperidines and their implication in design and synthesis of a conformationally-rigidified NK ₁ antagonist

Doi:10.1016/j.tetlet.2013.08.131
(2013)

Article Doi