Ene Reaction Mechanisms. 2. Regioselectivity with N-Aryl-N'-p-tosylsulfur Diimides as Enophiles. Crystal Structure of N-(Pentafluorophenyl)-N'-p-tosylsulfur Diimide

DOI: 10.1021/jo00165a010

Source and publish data:

Journal of Organic Chemistry p. 2833 - 2837 (1983)

Update date:2022-08-05

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Authors:

Muensterer, Heribert

Kresze, Guenter

Lamm, Viktor

Gieren, Alfred

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Article abstract of DOI:10.1021/jo00165a010

The ene reactions of sulfur diimides TosNSNAr (1;Ar = C6H5, 4-O2NC6H4, and C6F5) with 2-methyl-2-butene (2) have been investigated.The products undergo a <2,3> sigmatropic rearrangement.The structures of these rearranged products have been determined.Taki

Full text of DOI:10.1021/jo00165a010

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