Journal of Fluorine Chemistry p. 123 - 140 (1987)
Update date:2022-08-05
Topics:
Chen, Grace J.
Tamborski, Christ
The interaction between perfluoroorgano iodides (RfI where Rf = F(CF3)2C(CF2CF2)3, n-C6F13, n-C8F17, F(CF3)2COCF2CF2, F(CF3)2CO(CF2CF2)4 and C2H5OC(O)(CF2CF2)2OCF2CF2) with cadmium in an acetonitrile solvent media produces primarily the coupled products (RfRf, 72-90percent yield) in addition to minor quantities of the reduction products (RfH).On the other hand ICF2CF2I and ClCF2CFClI, by a 1,2-dehalogenation reaction, from the olefins CF2=CF2 and CF2=CFCl, respectively, as the principal products.The interaction of RfI compounds with cadmium in other solvent media, e.g. diethyl ether, tetrahydrofuran (YHF)), N,N-dimethylformamide (DMF), and bis(2-methoxyethyl)ether(diglyme) were examined and found to produce a different ratio of RfRf and RfH products.
View MoreContact:+49-4101-3053-0
Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Shanghai ZaiQi Bio-Tech Co., Ltd.,
Contact:+86-21-5482 4098
Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
zhenjiang runjing high purity chemical co ltd
Contact:+86-511-83361155
Address:No.8.haixi road,international chemical park
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
Twin International Co., Limited
Contact:+86-21-80309280
Address:No.345 Jinxiang Road, Jinqiao Export Processing Zone
Doi:10.1021/jo00168a005
(1983)Doi:10.1080/00397910500213880
(2005)Doi:10.1021/jo050488s
(2005)Doi:10.1016/j.tetlet.2005.08.106
(2005)Doi:10.1246/bcsj.72.1075
(1999)Doi:10.1016/j.tetlet.2005.08.112
(2005)
