THE REACTION OF N-MONO AND N,N-DISUBSTITUTED HYDROXYLAMINES WITH PALLADIUM CATALYST

Article abstract of DOI:10.1016/S0040-4039(00)81600-7

The Palladium catalyzed reactions of N,N-disubstituted and N-substituted hydroxylamines give the corresponding nitrones and azoxy compounds highly efficiently.The former reactions are performed in the presence of alkenes to give the cycloadducts which are valuable intermediates regio and stereoselectively.