Trimethylphosphine Polyhydrides of Tungsten and Rhenium

DOI: 10.1039/DT9850000587

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 587 - 590 (1985)

Update date:2022-07-30

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Authors:

Lyons, David

Wilkinson, Geoffrey

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Article abstract of DOI:10.1039/DT9850000587

The new compounds WH6(PMe3)3, ReH7(PMe3)2, ReH7(PMe3)2*PhNH2, and Re2H8(PMe3)4 have been synthesised.Improved syntheses of MH4(PMe3)4 (M=Mo or W) are also described.The complex WH6(PMe3)3 reacts with carbon dioxide under pressure to yield the fluxional mo

Full text of DOI:10.1039/DT9850000587

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