Solvolytic Hydroperoxide Rearrangements. 2. Oxa Bicyclic Hemiketal Peroxides from Homoallylic and Cyclopropylcarbinyl Precursors

DOI: 10.1021/jo00225a018

Source and publish data:

Journal of Organic Chemistry p. 5084 - 5088 (1985)

Update date:2022-08-03

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Authors:

Lillie, Thomas S.

Ronald, Robert C.

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Article abstract of DOI:10.1021/jo00225a018

Studies in this laboratory have resulted in the discovery of a novel hydrogen peroxide mediated ring expansion that is suitable for the synthesis of medium to large ring oxa bicyclic compounds.This rearrangement involves the solvolysis of homoallylic bros

Full text of DOI:10.1021/jo00225a018

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