Organic Letters p. 4329 - 4331 (2005)
Update date:2022-08-05
Topics:
Hu, Shanghui
Tat, David
Martinez, Carlos A.
Yazbeck, Daniel R.
Tao, Junhua
(Chemical Equation Presented) An efficient and practical chemoenzymatic method was developed for the preparation of a variety of chiral secondary amines. Here, oxalamic esters were identified as unique derivatives amenable to the enzyme-catalyzed kinetic resolution of racemic secondary amines. Both enantiomers of the amines were produced in high optical purity and yields after the cleavage of the oxalamic groups.
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