Journal of the Chemical Society. Chemical communications p. 107 - 108 (1984)
Update date:2022-08-03
Topics:
Hayashi, Tamio
Konishi, Mitsuo
Kumada, Makoto
The stereochemistry of the reaction of ?-allylpalladium complexes with nucleophiles has been elucidated using optically active (-)-(1S,2R,3R)-di-μ-chloro-bis(1-methyl-3-phenyl-?-allyl)dipalladium(II); dimethyl sodiomalonate and dimethylamine attack a carbon atom of the ?-allyl ligand from the side opposite to the palladium (inversion), and phenyl and allyl Grignard reagents attack the ?-allyl carbon atom from the same side as the palladium (retention).
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