Stereochemistry of the Reaction of an Optically Active ?-Allylpalladium Complex with Nucleophiles

DOI: 10.1039/c39840000107

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Journal of the Chemical Society. Chemical communications p. 107 - 108 (1984)

Update date:2022-08-03

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Authors:

Hayashi, Tamio

Konishi, Mitsuo

Kumada, Makoto

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Article abstract of DOI:10.1039/c39840000107

The stereochemistry of the reaction of ?-allylpalladium complexes with nucleophiles has been elucidated using optically active (-)-(1S,2R,3R)-di-μ-chloro-bis(1-methyl-3-phenyl-?-allyl)dipalladium(II); dimethyl sodiomalonate and dimethylamine attack a carbon atom of the ?-allyl ligand from the side opposite to the palladium (inversion), and phenyl and allyl Grignard reagents attack the ?-allyl carbon atom from the same side as the palladium (retention).

Full text of DOI:10.1039/c39840000107

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