Journal of Organic Chemistry p. 4621 - 4628 (1983)
Update date:2022-08-03
Topics:
Marino, Joseph P.
Linderman, Russell J.
The reactivity of substituted (α-carbethoxyvinyl)cuprate reagents with various electrophiles has been studied systematically.The reaction of this type of cuprate reagent with ketones and epoxides leads to high yields of isomerically pure olefinic esters, while its condensation reaction with aldehydes produced mixtures of isomers.The stereochemistry of the condensation reaction with carbonyl compounds is explained by a steric control mechanism involving an allenoate intermediate.
View MoreYancheng Creator Chemical Co., Ltd
Contact:0086-515-88710008 88710068 88710858 88710868
Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
Chongqing Changfeng Chemical Co., Ltd.
website:http://www.changfengchem.com
Contact:+86-23-67896333
Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
Contact:0086-29-89196322
Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Contact:86-931-8272767
Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
Wuxi Innopal International Trade CO.,LTD
Contact:+86-510-80711901-8003
Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China
Doi:10.1021/ol052542x
(2006)Doi:10.1021/jm501532z
(2014)Doi:10.1021/jo801659g
(2009)Doi:10.1016/j.cclet.2018.01.002
(2018)Doi:10.1021/jo00112a019
(1995)Doi:10.1016/j.tetlet.2011.03.007
(2011)
