Asymmetric C-H insertion of Rh(II) stabilized carbenoids into acetals: A C-H activation protocol as a Claisen condensation equivalent

DOI: 10.1016/j.jorganchem.2005.08.026

Source and publish data:

Journal of Organometallic Chemistry p. 6111 - 6124 (2005)

Update date:2022-08-05

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Authors:

Davies, Huw M.L.

Yang, Jaemoon

Nikolai, Joachim

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Article abstract of DOI:10.1016/j.jorganchem.2005.08.026

The dirhodium tetraprolinate, Rh₂(S-DOSP)₄ is an efficient catalyst in an enantioselective C-H activation protocol. Rh ₂(S-DOSP)₄ catalyzed decomposition of aryldiazoacetates or vinyldiazoacetates results in the

Full text of DOI:10.1016/j.jorganchem.2005.08.026

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