Journal of Organic Chemistry p. 11655 - 11658 (2017)
Update date:2022-08-04
Topics:
Wegener, Aaron
Miller, Kenneth A.
The first total synthesis of the marine natural product avrainvilleol is reported. The total synthesis features the first application of the transition-metal-free coupling of a tosyl hydrazone and a boronic acid to the preparation of a complex natural product, and the first example of this coupling with a hindered diortho substituted hydrazone substrate.
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