Tetrahedron Letters p. 2271 - 2274 (1983)
Update date:2022-09-26
Topics:
Kuzuya, Masayuki
Adachi, Michihiro
Noguchi, Akihiro
Okuda, Takachiyo
Acetone sensitized irradiation of novel 5,6-benzo-2-azabarrelenols were performed to afford di-?-methane photoproducts whose structures and ratios depended on the structural features and substituents; the phenyl substituent at C-8 rendered the pronounced effect on the formation of novel "cross-bonding" product through the imino-ether bridge, and importance of the product forming step for the observed regioselectivity was pointed out.
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