CLEAVAGE OF SILICON-VINYL CARBON BOND BY nBu4NF

DOI: 10.1016/S0040-4039(00)88048-X

Source and publish data:

Tetrahedron Letters p. 2877 - 2880 (1983)

Update date:2022-07-30

Topics:

Authors:

Oda, Hiroji

Sato, Mitsuyoshi

Morizawa, Yoshitomi

Oshima, Koichiro

Nozaki, Hitosi

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Article abstract of DOI:10.1016/S0040-4039(00)88048-X

Dimethylphenylsilyl- and diphenylmethylsilyl-vinyl carbon bonds are cleaved with ⁿBu4NF.Desilylation of 1-phenylthio-1-trimethylsilyl-1-alkenes in the presence of aldehyde moiety gives carbanion adducts.

Full text of DOI:10.1016/S0040-4039(00)88048-X

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