Inorganica Chimica Acta p. 1018 - 1022 (2006)
Update date:2022-08-03
Topics:
Hogarth, Graeme
Faulkner, Simon
Thermolysis of [CpRuCl(PPh3)2] and NaS 2CNPr2 or NaS2CNMeBu in methanol affords the ruthenium(II) dithiocarbamate complexes, [CpRu(PPh3)(S 2CNPr2)] and [CpRu(PPh3)(S2CNMeBu)], which have been crystallographically characterized. A similar treatment of two equivalents of [CpRuCl(PPh3)2] with the bis(dithiocarbamate) ligand derived from 1,3-homopiperazine affords [{CpRu(PPh3)}2(μ-S2CNC5H 10NCS2)].
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