
Journal of the Chemical Society. Chemical communications p. 848 - 849 (1983)
Update date:2022-08-04
Topics:
Hosokawa, Takahiro
Ohta, Toshiyuki
Murahashi, Shun-Ichi
Treatment of terminal olefins bearing electron-withdrawing groups with (R,R)-pentane-2,4-diol (2) in the presence of PdCl2-CuCl-O2 in 1,2-dimethoxyethane gives cyclic acetals such as (3) and (12b) via attack at the terminal carbon atom; the corresponding acetals are similarly formed from propane-1,3-diol (5) and ethylene glycol (8).
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Doi:10.1080/00397919608003873
(1996)Doi:10.1002/jhet.5570200548
(1983)Doi:10.1016/S0020-1693(00)81436-X
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(2005)Doi:10.1021/ja00318a019
(1984)Doi:10.1007/s10562-019-02909-1
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