Cationic Metal Nitrosyl Complexes. Part 5. Synthesis of Dinitrosylmolybdenum Compounds

DOI: 10.1039/DT9830001143

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1143 - 1148 (1983)

Update date:2022-08-03

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Authors:

Ballivet-Tkatchenko, Danielle

Bremard, Claude

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Article abstract of DOI:10.1039/DT9830001143

The reaction of in 1,2-dimethoxyethane (dme) affords monocationic (+) and dicationic (2+) species.The mechanism of chloride abstraction has been investigated by i.r., n.m.r., and u.v.-visible spectroscopy, conductimetry, and potentiometry.The dme solvates, when treated with nitriles or bipy, yield a series of cationic dinitrosylmolybdenum complexes.Some of the dicationic complexes catalyse the polymerisation of norbornadiene.The characterization of all new complexes is described.

Full text of DOI:10.1039/DT9830001143

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