Cationic Metal Nitrosyl Complexes. Part 5. Synthesis of Dinitrosylmolybdenum Compounds

DOI: 10.1039/DT9830001143

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1143 - 1148 (1983)

Update date:2022-08-03

Topics:

Authors:

Ballivet-Tkatchenko, Danielle

Bremard, Claude

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9830001143

The reaction of in 1,2-dimethoxyethane (dme) affords monocationic (+) and dicationic (2+) species.The mechanism of chloride abstraction has been investigated by i.r., n.m.r., and u.v.-visible spectroscopy, conductimetry, and potentiometry.The dme solvates, when treated with nitriles or bipy, yield a series of cationic dinitrosylmolybdenum complexes.Some of the dicationic complexes catalyse the polymerisation of norbornadiene.The characterization of all new complexes is described.

Full text of DOI:10.1039/DT9830001143

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:tris(benzonitrile)chlorodinitrosylmolybdenum⁽¹⁺⁾ perchlorate

Cas No:88042-44-8

R&D Labs maybe for 88042-44-8

Shao Xing Empire Import&Export CO.,ltd

Contact:86-575-82127757

Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China
Chengdu Biopurify Phytochemicals Ltd.

website:http://www.phytopurify.com

Contact:+86-28-82633397

Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China
Fujian Wanke Pharmaceutical Co., LTD.

Contact:+86-598-5026002

Address:Economic development zone,jiangle county
Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Jinan Jianfeng Chemical Co., Ltd

Contact:0086-531-88110457

Address:sales01(-a-t-)pharmachemm{dot}c+o+m

Relevant to this article

Crystalline low band-gap alternating indolocarbazole and benzothiadiazole-cored oligothiophene copolymer for organic solar cell applications

Doi:10.1039/b811031j
(2008)
The synthesis of some 3-thietanyl-substituted thiocarbamides and the study of their antioxidant activity

Doi:10.1134/S096554410905017X
(2009)
Cationic shape-persistent macrocycles: The unexpected formation of a nano-size supramolecular dimer

Doi:10.1021/ja057999g
(2006)
A bis(phosphinimino)methanide lanthanum amide as catalyst for the hydroamination/cyclisation, hydrosilylation and sequential hydroamination/ hydrosilylation catalysis

Doi:10.1039/b514242c
(2006)
S versus O alkylation and coordination in zinc complexes containing the bulky heteroscorpionate alkoxy ligand bis(3,5-dimethylpyrazol-2-yl) diphenylmethanol

Doi:10.1016/j.ica.2005.09.020
(2006)
A Novel Electrophilic Fluorination of Activated Aromatic Rings Using Acetyl Hypofluorite, Suitable also for Introducing (18)F into Benzene Nuclei

Doi:10.1021/jo00179a012
(1984)

Article Doi