Chemistry Letters p. 809 - 812 (1989)
Update date:2022-07-31
Topics:
Mitsunobu, Oyo
Yoshida, Makiko
Takiya, Masashi
Kubo, Keiji
Maruyama, Seitaro
et al.
1,5-Anhydro-4,6-O-benzylidene-2-deoxy-3-O-mesyl-D-ribo-hex-1-enitol reacted with alkylmagnesium bromides (RMgBr: R = C2H5-, (CH3)2CH-, or C2H5(CH3)CH-) to give the corresponding 1-β-C-glycopyranosides and 3-C-alkyl-D-arabino-hex-1-enitols, while the reaction with methylmagnesium bromide afforded 1-α-C- and 1-β-C-methyl-glycosides in a ratio of 1 : 1.5-2.On the other hand, when the reaction was carried out in the presence of CuI or CuBr-S(CH3)2, substitution took place at the C-3 position to afford the corresponding 3-C-methyl-D-arabino-hex-1-enitol.
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