Thermolysis of Sulfonyl Azides Bearing Nucleophilic Neighboring Groups. A Search for Anchimeric Assistance

DOI: 10.1021/jo00178a022

Source and publish data:

Journal of Organic Chemistry p. 683 - 687 (1984)

Update date:2022-08-04

Topics: Anchimeric Assistance

Authors:

McManus, Samuel P.

Smith, Maurice R.

Abramovitch, Rudolph A.

Offor, Mercy N.

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Article abstract of DOI:10.1021/jo00178a022

In a search for anchimeric assistance by n- or ?-donor neighboring groups in sulfonyl azide decompositions, 25 sulfonyl azides have been prepared and thermolyzed in 1-chloronaphthalene.First-order rate constants at 135 and 165 deg C were determined by mea

Full text of DOI:10.1021/jo00178a022

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