Journal of Organic Chemistry p. 683 - 687 (1984)
Update date:2022-08-04
Topics: Sulfonyl Azides (R-SO2-N3) Nucleophilic Neighboring Groups Anchimeric Assistance
McManus, Samuel P.
Smith, Maurice R.
Abramovitch, Rudolph A.
Offor, Mercy N.
In a search for anchimeric assistance by n- or ?-donor neighboring groups in sulfonyl azide decompositions, 25 sulfonyl azides have been prepared and thermolyzed in 1-chloronaphthalene.First-order rate constants at 135 and 165 deg C were determined by mea
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