Organometallics p. 520 - 524 (1984)
Update date:2022-07-30
Topics:
Green, Michael
Sarhan, Jamil K. K.
Al-Najjar, Ibrahim M.
The effect of gem-dialkyl groups and of other bulky substituents on the stability of a four-membered NCCPt ring system has been investigated, cf. the Thorpe-Ingold effect. It is observed that when an amine attacks alkene complexes cis-[PtCl2(alkene)Y], cyclic as opposed to acyclic products are more likely to be produced if the amine is secondary and the alkene is substituted.
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