Synthesis and theoretical analysis of the structures and bonding in five new neutral square planar bis[2,4-di(aryl)-1,3,5-triazapentadienato]nickel(II) complexes

Article abstract of DOI:10.1016/j.ica.2005.09.022

Solvothermal reactions in methanol of nickel acetate tetrahydrate, Ni(OAc)₂ ? 4H₂O, with benzonitrile derivatives NC(C₆H₄)X, where X is one of the electron withdrawing substituents -CN, -NO₂, or -CF₃, located at the m- or p-positions relative to -CN, yield complexes of the general formula Ni{HNC(R)-NC(R)-NH}₂. More specifically, 3-nitrobenzonitrile, 4-nitrobenzonitrile, 1,3-dicyanobenzene, 1,4-dicyanobenzene, and ααα-trifluoro-p-toluonitrile are found to react with Ni(OAc)₂ ? 4H₂O to yield Ni{HNC(R)-NC(R)-NH} ₂, where R = 3-(NO₂)C₆H₄, 4-(NO ₂)C₆H₄, 3-(CN)C₆H₄, 4-(CN)C₆H₄, or 4-(CF₃)C₆H ₄, respectively. Analogous reactions of nitriles lacking electron withdrawing groups do not occur under similar conditions. Solid-state structures have been determined for the complexes with p-NO₂, p-CN, and p-CF₃ substituents on the phenyl rings. In addition, we describe density functional theory (DFT) and natural bonding orbital theory (NBO) studies on a simplified analog of these compounds, aimed at understanding their molecular bonding. It is shown that the new compounds for which solid-state structures have been determined are model examples of coordination compounds containing robust ω-bonds.